The task is to identify the longest substring within a given string where all characters are unique, meaning each character appears only once. A substring is defined as a consecutive sequence of characters from the original string. To tackle this issue, techniques such as sliding window, hashing or a set data structure, along with a two-pointer approach, can be employed. To address this problem, follow these steps: Start by initializing two pointers at the beginning of the string. Expand the window by moving the right pointer and adding the character to the hash table or set. If a duplicate character is encountered, remove characters from the left until there are no duplicates remaining in the window. The maximum length of the window throughout this process will represent the length of the longest substring without repeating characters.