In SQL, JOIN and UNION are two different operations used for data manipulation and management within databases. A JOIN typically merges tables based on a common column, effectively connecting data from two or more tables when the join condition is met. For instance, if we have a Customers table and an Orders table, a JOIN would enable us to view all orders made by each customer. Conversely, a UNION operation is employed to combine rows from multiple tables into one, effectively merging the datasets into a single, larger dataset. In this case, all selected columns must share the same data type. This operation removes duplicate records, and the tables must have an identical number and type of columns. Therefore, if we had two tables, 'Old_Customers' and 'New_Customers', with the same structure but different entries, we could utilize UNION to generate a unified list of all our customers.